UER00228 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 7/10~1 H(+) + 1 NADH + 1 cobalt-precorrin-6A => 1 NAD(+) + 1 cobalt-precorrin-6B. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00233 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 2/7~1 ATP + 1 cob(I)yrinic acid a,c-diamide => 1 adenosylcob(III)yrinic acid a,c-diamide + 1 triphosphate. |
True - {{t}} |
True - {{t}} |
Confirmed presence |
|
UER00226 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 4/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin 4 => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 5A. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
VariantPath-2-UER00236 |
|
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
VariantPath-1-UER00236 |
|
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05227 |
ATP + Co(2+) + H(2)O + hydrogenobyrinic acid a,c-diamide = ADP + H(+) + cob(II)yrinate a,c-diamide + phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05815 |
2 ATP + 2 H(2)O + 2 L-glutamine + cob(III)yrinic acid = 2 ADP + 2 L-glutamate + cob(II)yrinate a,c-diamide + 2 phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
ULS00093 |
adenosylcobalamin from cob(II)yrinate a,c-diamide |
None - {{∅}} |
None - {{∅},{t}} |
Unexplained |
|
UER00230 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 9/10~1 cobalt-precorrin 8 => 1 cob(III)yrinic acid. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00225 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 3/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin 3 => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 4. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00229 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 8/10~2 S-adenosyl-L-methionine + 1 cobalt-precorrin-6B => 1 CO(2) + 2 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 8. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00219 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 8/10~1 precorrin-8X => 1 hydrogenobyrinic acid. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
ULS00173 |
sirohydrochlorin from precorrin-2 |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00234 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 3/7~4 ATP + 4 H(2)O + 4 L-glutamine + 1 adenosylcob(III)yrinic acid a,c-diamide => 4 ADP + 4 L-glutamate + 1 adenosylcobyrinic acid a,c-diamide + 4 phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR07773 |
S-adenosyl-L-methionine + cobalt-precorrin 5B = S-adenosyl-L-homocysteine + cobalt-precorrin-6A |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00211 |
precorrin-2 from uroporphyrinogen III: step 1/1~2 S-adenosyl-L-methionine + 1 uroporphyrinogen III => 2 S-adenosyl-L-homocysteine + 1 precorrin-2. |
True - {{t}} |
True - {{t}} |
Confirmed presence |
|
VariantPath-2-UPA00148 |
|
None - {{∅}} |
None - {{∅},{t}} |
Unexplained |
|
UER00214 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 3/10~1 S-adenosyl-L-methionine + 1 precorrin-3B => 1 S-adenosyl-L-homocysteine + 1 precorrin-4. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
VariantPath-1-UPA00148 |
|
None - {{∅}} |
None - {{∅},{t}} |
Unexplained |
|
UER00236 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 5/7~adenosylcobinamide + [ATP or GTP] => adenosylcobinamide phosphate + [ADP or GDP]. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR03947 |
NAD(+) + precorrin-2 = H(+) + NADH + sirohydrochlorin |
True - {{t}} |
True - {{t}} |
Confirmed presence |
|
UCR05150 |
NADP(+) + precorrin-6B = H(+) + NADPH + precorrin-6A |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
ULS00091 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route) |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00215 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 4/10~1 S-adenosyl-L-methionine + 1 precorrin-4 => 1 S-adenosyl-L-homocysteine + 1 precorrin-5. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00221 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 10/10~1 ATP + 1 Co(2+) + 1 H(2)O + 1 hydrogenobyrinic acid a,c-diamide => 1 ADP + 1 H(+) + 1 cob(II)yrinate a,c-diamide + 1 phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05149 |
2 S-adenosyl-L-methionine + precorrin-6B = CO(2) + 2 S-adenosyl-L-homocysteine + precorrin-8X |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00222 |
sirohydrochlorin from precorrin-2: step 1/1~1 NAD(+) + 1 precorrin-2 => 1 H(+) + 1 NADH + 1 sirohydrochlorin. |
True - {{t}} |
True - {{t}} |
Confirmed presence |
|
UCR05226 |
(R)-1-aminopropan-2-ol + adenosylcobyrinic acid a,c-diamide = H(2)O + adenosylcobinamide |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05813 |
2 S-adenosyl-L-methionine + cobalt-precorrin-6B = CO(2) + 2 S-adenosyl-L-homocysteine + cobalt-precorrin 8 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00217 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 6/10~1 H(+) + 1 NADPH + 1 precorrin-6A => 1 NADP(+) + 1 precorrin-6B. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
ULS00090 |
precorrin-2 from uroporphyrinogen III |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05808 |
S-adenosyl-L-methionine + cobalt-precorrin-2 = S-adenosyl-L-homocysteine + cobalt-factor III |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00561 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 5/10~1 H(2)O + 1 cobalt-precorrin 5A => 1 acetaldehyde + 1 cobalt-precorrin 5B. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00954 |
None~1 GTP + 1 adenosylcobinamide => 1 GDP + 1 adenosylcobinamide phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR07772 |
H(2)O + cobalt-precorrin 5A = acetaldehyde + cobalt-precorrin 5B |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05177 |
precorrin-8X = hydrogenobyrinic acid |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR03194 |
2 S-adenosyl-L-methionine + uroporphyrinogen III = 2 S-adenosyl-L-homocysteine + precorrin-2 |
True - {{t}} |
None - {{∅}} |
Missing |
|
UER00218 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 7/10~2 S-adenosyl-L-methionine + 1 precorrin-6B => 1 CO(2) + 2 S-adenosyl-L-homocysteine + 1 precorrin-8X. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05218 |
FMNH(2) + 2 cob(II)yrinate a,c-diamide = FMN + 2 H(+) + 2 cob(I)yrinic acid a,c-diamide |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00235 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 4/7~1 (R)-1-aminopropan-2-ol + 1 adenosylcobyrinic acid a,c-diamide => 1 H(2)O + 1 adenosylcobinamide. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00227 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 6/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin 5B => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin-6A. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00232 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 1/7~1 FMNH(2) + 2 cob(II)yrinate a,c-diamide => 1 FMN + 2 H(+) + 2 cob(I)yrinic acid a,c-diamide. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05217 |
H(+) + NADH + O(2) + precorrin-3A = H(2)O + NAD(+) + precorrin-3B |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05810 |
S-adenosyl-L-methionine + cobalt-precorrin 4 = S-adenosyl-L-homocysteine + cobalt-precorrin 5A |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05181 |
S-adenosyl-L-methionine + precorrin-4 = S-adenosyl-L-homocysteine + precorrin-5 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR03948 |
S-adenosyl-L-methionine + precorrin-2 = H(+) + S-adenosyl-L-homocysteine + precorrin-3A |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00223 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 1/10~1 Co(2+) + 1 sirohydrochlorin => 2 H(+) + 1 cobalt-precorrin-2. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00237 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 6/7~1 GTP + 1 adenosylcobinamide phosphate => 1 adenosylcobinamide-GDP + 1 diphosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00220 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 9/10~2 ATP + 2 H(2)O + 2 L-glutamine + 1 hydrogenobyrinic acid => 2 ADP + 2 L-glutamate + 1 hydrogenobyrinic acid a,c-diamide + 2 phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00216 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 5/10~1 H(2)O + 1 S-adenosyl-L-methionine + 1 precorrin-5 => 1 S-adenosyl-L-homocysteine + 1 acetate + 1 precorrin-6A. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05221 |
ATP + adenosylcobinamide = ADP + adenosylcobinamide phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00238 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 7/7~1 adenosylcobinamide-GDP + 1 alpha-ribazole => 1 GMP + 1 adenosylcobalamin. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05225 |
4 ATP + 4 H(2)O + 4 L-glutamine + adenosylcob(III)yrinic acid a,c-diamide = 4 ADP + 4 L-glutamate + adenosylcobyrinic acid a,c-diamide + 4 phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05222 |
GTP + adenosylcobinamide phosphate = adenosylcobinamide-GDP + diphosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR06558 |
GTP + adenosylcobinamide = GDP + adenosylcobinamide phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
ULS00092 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route) |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR08716 |
cobalt-factor III = cobalt-precorrin 3 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05219 |
S-adenosyl-L-homocysteine + acetate + precorrin-6A = H(2)O + S-adenosyl-L-methionine + precorrin-5 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05220 |
ATP + cob(I)yrinic acid a,c-diamide = adenosylcob(III)yrinic acid a,c-diamide + triphosphate |
True - {{t}} |
True - {{t}} |
Confirmed presence |
|
UCR05814 |
cobalt-precorrin 8 = cob(III)yrinic acid |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00953 |
None~1 ATP + 1 adenosylcobinamide => 1 ADP + 1 adenosylcobinamide phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00231 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 10/10~2 ATP + 2 H(2)O + 2 L-glutamine + 1 cob(III)yrinic acid => 2 ADP + 2 L-glutamate + 1 cob(II)yrinate a,c-diamide + 2 phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00213 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 2/10~1 H(+) + 1 NADH + 1 O(2) + 1 precorrin-3A => 1 H(2)O + 1 NAD(+) + 1 precorrin-3B. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05224 |
2 ATP + 2 H(2)O + 2 L-glutamine + hydrogenobyrinic acid = 2 ADP + 2 L-glutamate + hydrogenobyrinic acid a,c-diamide + 2 phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05807 |
Co(2+) + sirohydrochlorin = 2 H(+) + cobalt-precorrin-2 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05180 |
S-adenosyl-L-methionine + precorrin-3B = S-adenosyl-L-homocysteine + precorrin-4 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05809 |
S-adenosyl-L-methionine + cobalt-precorrin 3 = S-adenosyl-L-homocysteine + cobalt-precorrin 4 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UPA00148 |
adenosylcobalamin biosynthesis~Biosynthesis of adenosylcobalamin (vitamin B12), a modified tetrapyrrole cofactor. Adenosylcobalamin belongs to the same class of compounds as heme, chlorophyll, siroheme, and coenzyme F430. Most prokaryotic organisms as well as animals (including human) and protists have enzyme that require adenosylcobalamin as cofactor, whereas plants and fungi are thought not to use it. It is one of the most structurally complex protein cofactors ans its biosynthesis remains one of the most enigmatic and exigent metabolic pathways in nature, requiring around 30 enzymes. Two distinct yet similar route exist, known as the oxygene-dependent (aerobic route) and oxygen-independent (anaerobic route) pathways. These pathways diverge at precorrin-2 and merge again at adenosylcobyrate. The major difference between these two routes include the timing of cobalt insertion, the requirement for oxygen and the nature of the extruded carbon fragment which is lost during the ring construction process [McGoldrick et al, 2005]. |
None - {{∅}} |
None - {{∅},{t}} |
Unexplained |
|
UCR05812 |
H(+) + NADH + cobalt-precorrin-6A = NAD(+) + cobalt-precorrin-6B |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00212 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 1/10~1 S-adenosyl-L-methionine + 1 precorrin-2 => 1 H(+) + 1 S-adenosyl-L-homocysteine + 1 precorrin-3A. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00224 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 2/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin-2 => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 3. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05223 |
GMP + adenosylcobalamin = adenosylcobinamide-GDP + alpha-ribazole |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|