UER00226 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 4/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin 4 => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 5A. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
VariantPath-2-UER00236 |
|
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
VariantPath-1-UER00236 |
|
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05227 |
ATP + Co(2+) + H(2)O + hydrogenobyrinic acid a,c-diamide = ADP + H(+) + cob(II)yrinate a,c-diamide + phosphate |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05815 |
2 ATP + 2 H(2)O + 2 L-glutamine + cob(III)yrinic acid = 2 ADP + 2 L-glutamate + cob(II)yrinate a,c-diamide + 2 phosphate |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
ULS00093 |
adenosylcobalamin from cob(II)yrinate a,c-diamide |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00230 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 9/10~1 cobalt-precorrin 8 => 1 cob(III)yrinic acid. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00234 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 3/7~4 ATP + 4 H(2)O + 4 L-glutamine + 1 adenosylcob(III)yrinic acid a,c-diamide => 4 ADP + 4 L-glutamate + 1 adenosylcobyrinic acid a,c-diamide + 4 phosphate. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR07773 |
S-adenosyl-L-methionine + cobalt-precorrin 5B = S-adenosyl-L-homocysteine + cobalt-precorrin-6A |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
VariantPath-2-UPA00148 |
|
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00214 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 3/10~1 S-adenosyl-L-methionine + 1 precorrin-3B => 1 S-adenosyl-L-homocysteine + 1 precorrin-4. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
VariantPath-1-UPA00148 |
|
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00236 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 5/7~adenosylcobinamide + [ATP or GTP] => adenosylcobinamide phosphate + [ADP or GDP]. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05150 |
NADP(+) + precorrin-6B = H(+) + NADPH + precorrin-6A |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
ULS00091 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route) |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00215 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 4/10~1 S-adenosyl-L-methionine + 1 precorrin-4 => 1 S-adenosyl-L-homocysteine + 1 precorrin-5. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00221 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 10/10~1 ATP + 1 Co(2+) + 1 H(2)O + 1 hydrogenobyrinic acid a,c-diamide => 1 ADP + 1 H(+) + 1 cob(II)yrinate a,c-diamide + 1 phosphate. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05149 |
2 S-adenosyl-L-methionine + precorrin-6B = CO(2) + 2 S-adenosyl-L-homocysteine + precorrin-8X |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00222 |
sirohydrochlorin from precorrin-2: step 1/1~1 NAD(+) + 1 precorrin-2 => 1 H(+) + 1 NADH + 1 sirohydrochlorin. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05813 |
2 S-adenosyl-L-methionine + cobalt-precorrin-6B = CO(2) + 2 S-adenosyl-L-homocysteine + cobalt-precorrin 8 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
ULS00090 |
precorrin-2 from uroporphyrinogen III |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05808 |
S-adenosyl-L-methionine + cobalt-precorrin-2 = S-adenosyl-L-homocysteine + cobalt-factor III |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00561 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 5/10~1 H(2)O + 1 cobalt-precorrin 5A => 1 acetaldehyde + 1 cobalt-precorrin 5B. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR07772 |
H(2)O + cobalt-precorrin 5A = acetaldehyde + cobalt-precorrin 5B |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05177 |
precorrin-8X = hydrogenobyrinic acid |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR03194 |
2 S-adenosyl-L-methionine + uroporphyrinogen III = 2 S-adenosyl-L-homocysteine + precorrin-2 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05218 |
FMNH(2) + 2 cob(II)yrinate a,c-diamide = FMN + 2 H(+) + 2 cob(I)yrinic acid a,c-diamide |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00235 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 4/7~1 (R)-1-aminopropan-2-ol + 1 adenosylcobyrinic acid a,c-diamide => 1 H(2)O + 1 adenosylcobinamide. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00227 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 6/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin 5B => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin-6A. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05181 |
S-adenosyl-L-methionine + precorrin-4 = S-adenosyl-L-homocysteine + precorrin-5 |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00237 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 6/7~1 GTP + 1 adenosylcobinamide phosphate => 1 adenosylcobinamide-GDP + 1 diphosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00220 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 9/10~2 ATP + 2 H(2)O + 2 L-glutamine + 1 hydrogenobyrinic acid => 2 ADP + 2 L-glutamate + 1 hydrogenobyrinic acid a,c-diamide + 2 phosphate. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00216 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 5/10~1 H(2)O + 1 S-adenosyl-L-methionine + 1 precorrin-5 => 1 S-adenosyl-L-homocysteine + 1 acetate + 1 precorrin-6A. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR06558 |
GTP + adenosylcobinamide = GDP + adenosylcobinamide phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
ULS00092 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route) |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05220 |
ATP + cob(I)yrinic acid a,c-diamide = adenosylcob(III)yrinic acid a,c-diamide + triphosphate |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00953 |
None~1 ATP + 1 adenosylcobinamide => 1 ADP + 1 adenosylcobinamide phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00231 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 10/10~2 ATP + 2 H(2)O + 2 L-glutamine + 1 cob(III)yrinic acid => 2 ADP + 2 L-glutamate + 1 cob(II)yrinate a,c-diamide + 2 phosphate. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05224 |
2 ATP + 2 H(2)O + 2 L-glutamine + hydrogenobyrinic acid = 2 ADP + 2 L-glutamate + hydrogenobyrinic acid a,c-diamide + 2 phosphate |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05180 |
S-adenosyl-L-methionine + precorrin-3B = S-adenosyl-L-homocysteine + precorrin-4 |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UPA00148 |
adenosylcobalamin biosynthesis~Biosynthesis of adenosylcobalamin (vitamin B12), a modified tetrapyrrole cofactor. Adenosylcobalamin belongs to the same class of compounds as heme, chlorophyll, siroheme, and coenzyme F430. Most prokaryotic organisms as well as animals (including human) and protists have enzyme that require adenosylcobalamin as cofactor, whereas plants and fungi are thought not to use it. It is one of the most structurally complex protein cofactors ans its biosynthesis remains one of the most enigmatic and exigent metabolic pathways in nature, requiring around 30 enzymes. Two distinct yet similar route exist, known as the oxygene-dependent (aerobic route) and oxygen-independent (anaerobic route) pathways. These pathways diverge at precorrin-2 and merge again at adenosylcobyrate. The major difference between these two routes include the timing of cobalt insertion, the requirement for oxygen and the nature of the extruded carbon fragment which is lost during the ring construction process [McGoldrick et al, 2005]. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00212 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 1/10~1 S-adenosyl-L-methionine + 1 precorrin-2 => 1 H(+) + 1 S-adenosyl-L-homocysteine + 1 precorrin-3A. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00224 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 2/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin-2 => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 3. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00228 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 7/10~1 H(+) + 1 NADH + 1 cobalt-precorrin-6A => 1 NAD(+) + 1 cobalt-precorrin-6B. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00233 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 2/7~1 ATP + 1 cob(I)yrinic acid a,c-diamide => 1 adenosylcob(III)yrinic acid a,c-diamide + 1 triphosphate. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00225 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 3/10~1 S-adenosyl-L-methionine + 1 cobalt-precorrin 3 => 1 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 4. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00229 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 8/10~2 S-adenosyl-L-methionine + 1 cobalt-precorrin-6B => 1 CO(2) + 2 S-adenosyl-L-homocysteine + 1 cobalt-precorrin 8. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00219 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 8/10~1 precorrin-8X => 1 hydrogenobyrinic acid. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
ULS00173 |
sirohydrochlorin from precorrin-2 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00211 |
precorrin-2 from uroporphyrinogen III: step 1/1~2 S-adenosyl-L-methionine + 1 uroporphyrinogen III => 2 S-adenosyl-L-homocysteine + 1 precorrin-2. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR03947 |
NAD(+) + precorrin-2 = H(+) + NADH + sirohydrochlorin |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05226 |
(R)-1-aminopropan-2-ol + adenosylcobyrinic acid a,c-diamide = H(2)O + adenosylcobinamide |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00217 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 6/10~1 H(+) + 1 NADPH + 1 precorrin-6A => 1 NADP(+) + 1 precorrin-6B. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00954 |
None~1 GTP + 1 adenosylcobinamide => 1 GDP + 1 adenosylcobinamide phosphate. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00218 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 7/10~2 S-adenosyl-L-methionine + 1 precorrin-6B => 1 CO(2) + 2 S-adenosyl-L-homocysteine + 1 precorrin-8X. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00232 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 1/7~1 FMNH(2) + 2 cob(II)yrinate a,c-diamide => 1 FMN + 2 H(+) + 2 cob(I)yrinic acid a,c-diamide. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05217 |
H(+) + NADH + O(2) + precorrin-3A = H(2)O + NAD(+) + precorrin-3B |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05810 |
S-adenosyl-L-methionine + cobalt-precorrin 4 = S-adenosyl-L-homocysteine + cobalt-precorrin 5A |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR03948 |
S-adenosyl-L-methionine + precorrin-2 = H(+) + S-adenosyl-L-homocysteine + precorrin-3A |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UER00223 |
cob(II)yrinate a,c-diamide from sirohydrochlorin (anaerobic route): step 1/10~1 Co(2+) + 1 sirohydrochlorin => 2 H(+) + 1 cobalt-precorrin-2. |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05221 |
ATP + adenosylcobinamide = ADP + adenosylcobinamide phosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00238 |
adenosylcobalamin from cob(II)yrinate a,c-diamide: step 7/7~1 adenosylcobinamide-GDP + 1 alpha-ribazole => 1 GMP + 1 adenosylcobalamin. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05225 |
4 ATP + 4 H(2)O + 4 L-glutamine + adenosylcob(III)yrinic acid a,c-diamide = 4 ADP + 4 L-glutamate + adenosylcobyrinic acid a,c-diamide + 4 phosphate |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05222 |
GTP + adenosylcobinamide phosphate = adenosylcobinamide-GDP + diphosphate |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR08716 |
cobalt-factor III = cobalt-precorrin 3 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05219 |
S-adenosyl-L-homocysteine + acetate + precorrin-6A = H(2)O + S-adenosyl-L-methionine + precorrin-5 |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05814 |
cobalt-precorrin 8 = cob(III)yrinic acid |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UER00213 |
cob(II)yrinate a,c-diamide from precorrin-2 (aerobic route): step 2/10~1 H(+) + 1 NADH + 1 O(2) + 1 precorrin-3A => 1 H(2)O + 1 NAD(+) + 1 precorrin-3B. |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05807 |
Co(2+) + sirohydrochlorin = 2 H(+) + cobalt-precorrin-2 |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05809 |
S-adenosyl-L-methionine + cobalt-precorrin 3 = S-adenosyl-L-homocysteine + cobalt-precorrin 4 |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|
UCR05812 |
H(+) + NADH + cobalt-precorrin-6A = NAD(+) + cobalt-precorrin-6B |
None - {{∅}} |
None - {{∅}} |
Unexplained |
|
UCR05223 |
GMP + adenosylcobalamin = adenosylcobinamide-GDP + alpha-ribazole |
None - {{∅}} |
True - {{t}} |
Unconfirmed presence |
|